SOLVENTS
In addition to etching processes, the 
solubilities of substances often play a decisive role in microstructuring. This does not 
only apply to the structuring of organic layers, but to all 
wet chemical etching processes: In addition to chemical removal, the 
etched substances must be dissolved in the etching medium. 
> Solvents: theory and application
 
                                
                                                
Overview of the physical properties of the solvents.
                                            
                        Filter
            
                                –
                            
                        
                                                    
                                            
                                
                                
                                    
                                    Acetone MC - 2.50 l - ULSI - EUD/EVE!
                                
                            
            
                                    
                            
    
                                
                                    
                        MACU1025
        
    
                                                                        
                                                                                                                                    Manufacturer:
                                                
                                                    MicroChemicals GmbH
                                                
                                                                                                     | 
                                                                                                                                            Bottle size:
                                                
                                                    2.50 l
                                                
                                                                                                     | 
                                                                                                                                            Purity:
                                                
                                                    ULSI
                                                
                                                                                                                                                                        
                                
        Acetone
CH3COCH3
 
General Information
Acetone removes organic impurities from substrates and is well suited for greasy/oily contaminations. However, its large vapour pressure causes rapid drying together with a resorption of the contaminants on the substrate. Therefore an immediately subse¬quent rinsing step is recommended with a higher boiling solvent such as isopropanol.
Acetone is not well-suited as lift-off medium due to the high fire danger when heated and the trend of particles to be lifted to resorb onto the substrate.
Product Properties
Density: 0.79 g/cm^3
Melting point: 95°C
Boiling point: 56°C
Flash point: < -18°C
Vapour pressure @ 20°C: 244 hPa
 
Acetone Molecule
Further Information
MSDS:
Safety Data Sheet Acetone english (TECHNIC France)
Sicherheitsdatenblatt Aceton german (TECHNIC France)
Safety Data Sheet Acetone english (MicroChemicals GmbH)
Sicherheitsdatenblatt Aceton german (MicroChemicals GmbH)
Specs:
Specs Acetone ULSI (TECHNIC France)
Specs Acetone VLSI (TECHNIC France)
Specs Acetone ULSI (MicroChemicals GmbH)
Application Notes:
Solvents english
Lösemittel german
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    AZ EBR 70/30 - 1.00 l
                                
                            
            
                                    
                            
    
                                
                                    
                        10703021
        
    
                                                                        
                                                                                                                                    Bottle size:
                                                
                                                    1.00 l
                                                
                                                                                                                                                                        
                                
        AZ® EBR Solvent 70/30
1-methoxy-2-propyl-acetate
 
General Information
AZ® EBR Solvent 70/30 is the main solvent/thinner of almost all AZ® and TI photoresists due to its low vapour pressure and its suppression of particle formation in the (further diluted) resist. Additionally, PGMEA is often used for edge bead removal, since its low vapour pressure prevents further thinning of the coated resist film. 
Product Properties
Density: 0.97 g/cm3
Melting point: -66°C
Boiling point: 125°C
Flash point: 45°C
Vapour pressure @ 20°C: 5 hPa
 
PGMEA Molecule 
Further Information
MSDS:
Safety Data Sheet AZ® EBR Solvent 70/30 english
Sicherheitsdatenblatt AZ® EBR Solvent 70/30 german  
TDS:
Technical Data Sheet AZ® EBR Solvent 70/30 english
Information AZ® EBR Solvent 70/30 english
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    AZ EBR Solvent - 5.00 l
                                
                            
            
                                    
                            
    
                                
                                    
                        1000002
        
    
                                                                        
                                                                                                                                    Bottle size:
                                                
                                                    5.00 l
                                                
                                                                                                                                                                        
                                
        AZ® EBR Solvent
1-methoxy-2-propyl-acetate
 
General Information
AZ® EBR Solvent is the main solvent/thinner of almost all AZ® and TI photoresists due to its low vapour pressure and its suppression of particle formation in the (further diluted) resist. Additionally, PGMEA is often used for edge bead removal, since its low vapour pressure prevents further thinning of the coated resist film. 
Product Properties
Density: 0.97 g/cm3
Melting point: -66°C
Boiling point: 125°C
Flash point: 45°C
Vapour pressure @ 20°C: 5 hPa
 
PGMEA Molecule 
Further Information
MSDS:
Safety Data Sheet AZ® EBR Solvent english
Sicherheitsdatenblatt AZ® EBR Solvent german  
TDS:
Technical Data Sheet AZ® EBR Solvent english
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    Cyclopentanon - 2.50 l - ULSI
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        TCYU1025
        
    
                                                                        
        Cyclopentanone
C5H8O
 
General Information
Cyclopentanone is often used in conjunction with epoxy-based resist formulations, as well as an organic developer for cross-linking photoresists such as e-beam resists. 
Product Properties
Density: 0.88 g/cm3
Melting point: -77°C
Boiling point: 127°C
Flash point: 27°C
Vapour pressure @ 20°C: 10.7 hPa
 
Cyclopentanone Molecule
Further Information
MSDS:
Safety Data Sheet Cyclopentanon (ULSI) english
Sicherheitsdatenblatt Cyclopentanon (ULSI) german  
Specs:
Specs Cyclopentanon (ULSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    DMSO - 2.50 l - ULSI
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        MDMU1025
        
    
                                                                        
        DMSO
Dimethyl Sulfoxide
 
General Information
Due to its low vapour pressure and its water solubility, DMSO is an excellent stripper for resists respectively Lift-off media and is a non-toxic substitute for the NMP, which has been classified as toxic since a while. The optional addition of Cyclopentanone or MEK increases the performance of the stripper for certain applications and significantly lowers the melting point of pure DMSO. 
NOTE:
The solvent DMSO (dimethyl sulfoxide) has a melting point just below room temperature, so it can possi¬bly freeze in storage in cooler rooms. Thawing may require several days, but afterwards the product can still be used as it is.
For more details please download the info letter.
Product Properties
Density: 1.1 g/cm3
Melting point: 18°C
Boiling point: 189°C
Flash point: 87°C
Vapour pressure @ 20°C: 0.56 hPa
 
DMSO Molecule 
Further Information
MSDS:
Safety Data Sheet DMSO (ULSI) english
Sicherheitsdatenblatt DMSO (ULSI) german  
Specs:
Specs DMSO (ULSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german
Photoresist Removal english
Fotolack entfernen german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    Isopropyl Alcohol MC - 2.50 l - ULSI
                                
                            
            
                                    
                            
    
                                
                                    
                        MIPU1025
        
    
                                                                        
                                                                                                                                    Manufacturer:
                                                
                                                    MicroChemicals GmbH
                                                
                                                                                                     | 
                                                                                                                                            Bottle size:
                                                
                                                    2.50 l
                                                
                                                                                                     | 
                                                                                                                                            Purity:
                                                
                                                    ULSI
                                                
                                                                                                                                                                        
                                
        Isopropyl Alcohol
IPA, 2-propanol
 
General Information
Isopropyl alcohol is well-suited for rinsing contaminated acetone as well as removing particles from surfaces. Therefore, this solvent is often used in the second substrate cleaning step after acetone. Additionally, Isopropyl alcohol is used as additive for anisotropic Si-etching. 
Product Properties
Density: 0.78 g/cm3
Melting point: - 88°C
Boiling point: 82°C
Flash point: 13°C
Vapour pressure @ 20°C: 43 hPa
 
Isopropyl alcohol Molecule*
Further Information
MSDS:
Safety Data Sheet Isopropyl Alcohol (ULSI) english
Sicherheitsdatenblatt Isopropyl Alcohol (ULSI) german
Safety Data Sheet Isopropyl Alcohol (VLSI) english
Sicherheitsdatenblatt Isopropyl Alcohol (VLSI) german  
Specs:
Specs Isopropyl Alcohol (ULSI)
Specs Isopropyl Alcohol (VLSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    MEK - 2.50 l - ULSI - EVE/EUD!
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        MMEU1025
        
    
                                                                        
        MEK
Methyl Ethyl Ketone
 
General Information
MEK (methyl ethyl ketone) with its low boiling point can be used as MicroChemicals additional thinner for spray coating resists, which require a fast resist film drying on the substrate. 
Product Properties
Density: 0.81 g/cm3
Melting point: -86°C
Boiling point: 80°C
Flash point: -4°C
Vapour pressure @ 20°C: 105 hPa
 
MEK Molecule 
Further Information
MSDS:
Safety Data Sheet MEK (ULSI) english
Sicherheitsdatenblatt MEK (ULSI) german  
Specs:
Specs MEK (ULSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    Methanol - 2.50 l - VLSI - EVE/EUD!
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        TMLU1025
        
    
                                                                        
        Methanol
Methylalcohol
 
General Information
Methanol can be used for improved substrate cleaning due to its good dissolving power for contaminated acetone in a three-stage cleaning process (acetone à methanol à isopropyl alcohol). Due to its toxicity, its application should be weighed against its potential benefits. 
Product Properties
Density: 0.79 g/cm3
Melting point: -98°C
Boiling point: 65°C
Flash point: 11°C
Vapour pressure @ 20°C: 129 hPa
 
Methanol Molecule 
Further Information
MSDS:
Safety Data Sheet Methanol (VLSI) english
Sicherheitsdatenblatt Methanol (VLSI) german  
Specs:
Specs Methanol (VLSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    MIBK - 2.50 l - VLSI - EVE/EUD!
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        TMIV1025
        
    
                                                                        
        MIBK
Methyl Isobuthyl Ketone
 
General Information
MIBK is used in microelectronics as a developer for e-beam resists among other things.
Product Properties
Density: 0.80 g/cm3
Melting point: -80°C
Boiling point: 116°C
Flash point: 14°C
Vapour pressure @ 20°C: 19 hPa
 
MIBK Molecule 
Further Information
MSDS:
Safety Data Sheet MIBK (VLSI) english
Sicherheitsdatenblatt MIBK (VLSI) german  
Specs:
Specs MIBK (VLSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    n-Butylacetat - 5.00 l - VLSI
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        TNBAV1050
        
    
                                                                        
        Butyl Acetate
C6H12O2
 
General Information
Butyl Acetate is a solvent with a boiling point of 127°C. The vapour pressure at room temperature is 10.7 hPa. Butyl Acetate has the chemical formula C6H12O2. It can be easily solved in nonpolar (organic) solvents, but fairly bad in water (4.3 g per Litre).
Product Properties
Density: 0.88 g/cm3
Melting point: -77°C
Boiling point: 127°C
Flash point: 27°C
Vapour pressure @ 20°C: 10.7 hPa
Further Information
MSDS:
Safety Data Sheet Butyl Acetate (VLSI) english
Sicherheitsdatenblatt Butyl Acetate (VLSI) german  
Specs:
Specs Butyl Acetate (VLSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    PGMEA - 5.00 l - ULSI
                                
                            
            
                                    
                                                                                                                                                                
                                
                            
    
                                
                                    
                        MPGU1050
        
    
                                                                        
        PGMEA
1-methoxy-2-propyl-acetate
 
General Information
PGMEA is the main solvent/thinner of almost all AZ® and TI photoresists due to its low vapour pressure and its suppression of particle formation in the (further diluted) resist. Additionally, PGMEA is often used for edge bead removal, since its low vapour pressure prevents further thinning of the coated resist film. 
Product Properties
Density: 0.97 g/cm3
Melting point: -66°C
Boiling point: 125°C
Flash point: 45°C
Vapour pressure @ 20°C: 5 hPa
 
PGMEA Molecule 
Further Information
MSDS:
Safety Data Sheet PGMEA (ULSI) english
Sicherheitsdatenblatt PGMEA (ULSI) german  
Specs:
Specs PGMEA (ULSI)  
Application Notes:
Solvents: Theory and Application english
Lösemittel: Theorie und Anwendung german  
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                          
                                
                                
                                    
                                    TechniStrip Micro D350 - 2.50 l - ULSI
                                
                            
            
                                    
                            
    
                                
                                    
                        TD350U1025
        
    
                                                                        
                                                                                                                                    Bottle size:
                                                
                                                    2.50 l
                                                
                                                                                                                                                                        
                                
        TechniStrip Micro D350
DMSO-based Stripper
 
General Information
TechniStrip® Micro D350 is a DMSO-based stripper and is a very well suited non-toxic substitute for the NMP that is regarded as toxic since a while. As a stripper or as lift off media, TechniStrip® Micro D350 can be regarded as a non toxic alternative to NMP. Mixtures with Cyclopentanone or with MEK even increase the strip performance of this product. 
NOTE:
The solvent TechniStrip® Micro D350 has a melting point just below room temperature, so it can possi¬bly freeze in storage in cooler rooms. Thawing may require several days, but afterwards the product can still be used as it is.
For more details please download the info letter.
Further Information
MSDS:
Safety Data Sheet TechniStrip Micro D350 (ULSI) english
Sicherheitsdatenblatt TechniStrip Micro D350 (ULSI) german  
TDS:
Technical Data Sheet TechniStrip Micro D350 (ULSI) english  
Specs:
Specs TechniStrip Micro D350 (ULSI)  
Application Notes:
Photoresist Removal english
Fotolack entfernen german
Further Information about Processing
    
                                            
                                                                
                                    
                                
                                                           
                                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                            
                                                                                                                            
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                            
                                                                                                                            
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                            
                                                                                                                            
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                            
                                                                                                                            
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
             
                                                         
                                                                            
                                            
        
                        
                                                                                                
                                                                                                                                                
    
        
        
                                    
        
                            
                        
                        
    
    
    
        
                
        
                
                    
            